
Candles have been a source of fascination for scientists for hundreds of years, with the flame and its combustion being the subject of many experiments. The burning of a candle involves a complex process of heat, light, and chemical reactions. When a candle burns, the wax melts and evaporates, travelling up the wick to be burned. This process releases heat and light, and the wax vapour combines with oxygen in the air to produce carbon dioxide and water vapour. However, burning candles can also present safety concerns, with the potential for fire hazards and the release of harmful substances. Therefore, it is important to understand how candles burn and the factors that can cause them to go out, such as the type of wax, wick, and fragrance used, as well as the burning duration and external factors like gravity.
| Characteristics | Values |
|---|---|
| What happens when a candle burns? | Most of a candle's matter goes into the air as carbon dioxide and water vapour. |
| What is a candle made of? | Wax, which is made of hydrogen and carbon. |
| What is the purpose of the wick? | The wick, made of cotton or metal, draws the liquid wax up and the wax then evaporates and burns. |
| What happens to the wax? | The heat of the flame turns the wax into a hot gas, breaking down the hydrogen and carbon atoms. |
| What happens when a candle goes out? | A candle may go out due to a lack of fuel, oxygen, or heat. |
| How can you prevent a candle from going out? | Use a self-extinguishing wick, trim the wick regularly, and avoid non-combustible fragrance oils. |
| What is candle tunneling? | Candle tunneling occurs when a hole forms down the centre, leaving unused wax at the edges. |
| How can you fix candle tunneling? | Melt the outer wax surrounding the tunnel to make the surface even again. |
| What safety precautions should be taken? | Never leave a candle burning unattended, avoid flammable objects, and adhere to recommended burn times. |
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What You'll Learn

The chemical composition of candles
Candles have been a part of human civilization for thousands of years, used as sources of light, warmth, and ambiance. The science behind how candles work is complex and fascinating.
Candle Composition
At the heart of every candle is its wax, which acts as the fuel source for the flame. Various types of wax are used in candle-making, each with unique properties and characteristics. The most common types of wax used are paraffin wax, beeswax, stearin wax, soy wax, and tallow.
Paraffin Wax
Paraffin wax, derived from petroleum or crude oil, is the most commonly used type of wax due to its affordability and versatility. It is a complex mixture of hydrocarbons, with different molecular weights and structures determining its melting point, hardness, and other physical properties. It burns clean and creates a wonderful base for oils and botanicals, making it ideal for scented candles.
Beeswax
Beeswax is another popular type of wax used in candles. Honey bees are the only bees that produce beeswax. Introduced in Europe during the Middle Ages, beeswax was expensive and limited, so it was mainly used for special occasions. Today, beeswax is widely used as it is considered safer and burns cleanly.
Stearin Wax
Stearin wax is made by extracting stearic acid from animal fatty acids and was widely used in Europe. It has a high melting point and is often combined with other waxes to regulate their melting points.
Soy Wax
Soy wax, derived from soybean oil, is a popular eco-friendly alternative to paraffin wax. It is known for its clean-burning and renewable nature, making it a sustainable option for candle-making.
Tallow
Tallow is rendered from animal fats and was historically used by Ancient Egyptians and Early Romans. It fell out of favour due to the unpleasant smell and smoke it produced when burned.
Additional Components
Candles can also contain other components such as wicks, colourants, and fragrances. Wicks are typically made from braided cotton, which curls over and is completely consumed. Fragrances can be natural, derived from essential oils, or synthetic, made from aroma chemicals. Colourants and fragrances can alter the chemical composition of the wax, affecting its melting point, viscosity, and combustion characteristics.
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How candles burn in microgravity
Candles burn differently in microgravity than on Earth. On Earth, a candle flame is teardrop-shaped due to gravity-driven buoyant convection, which carries combustion products (carbon dioxide, water vapour, and soot) away from the flame.
In microgravity, there is no buoyant convection, so the flame forms a sphere around the wick. Diffusion feeds oxygen to the flame and allows carbon dioxide to move away from the point of combustion, but at a slower rate than on Earth. The flame is almost invisible, appearing as a blue colour, and burns at a lower temperature. It produces little to no smoke, and the slower gas exchange from diffusion can produce a soot-free flame. However, when burning stops at the tip of the flame, soot production begins.
Experiments conducted by NASA in the late 1990s first revealed the behaviour of candle flames in microgravity. These experiments showed that a candle flame in microgravity is spherical, rather than elongated or teardrop-shaped as on Earth.
Interestingly, candles that burn for 10 minutes or less on Earth can produce a flame for up to 45 minutes in microgravity, according to Dr Shannon Lucid's findings on the Mir Space Station. This may be due to the slower rate of burning in microgravity. When the flame is extinguished, a white ball surrounding the candle tip may remain, possibly consisting of flammable wax vapour.
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Why candles go out
A candle's combustion process requires fuel, oxygen, and heat. If any of these elements are missing or if the balance is disrupted, the flame will go out.
Candles with self-extinguishing wicks, like those made from zinc or tin, are more likely to go out on their own. The type of wax and material used for the wick also play a role in a candle's self-extinguishing capabilities. For example, paraffin wax has a specific burn time and may not extinguish itself before reaching the candle's base. Container candles with sturdy wax that hardens around a metal wick tend to burn down completely before going out.
If you're using the wrong type of wick for your wax and fragrance combination, your wick might "bridge." This happens when the wick doesn't self-trim as it burns, often because the chemical treatment on the wick is too strong for the candle material. A bridging wick can sometimes bend over so far that it falls into the melt pool, extinguishing the flame. Similarly, if the wick wax has a low melting point, the wick may become unstable and fall into the melt pool, removing both oxygen and heat from the fire triangle.
To prevent tunneling, burn your candle long enough each time so that the entire top surface of wax is melted. This is especially important the first time you burn your candle. A good rule of thumb is to burn your candle for one hour per inch of its diameter.
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How to prevent candle tunneling
Candle tunneling is a common issue that occurs when a hole forms down the center, leaving unused wax at the edges. This happens when only a small portion of the wax surrounding the wick melts while the candle is lit. Tunneling can drastically reduce the total burn time of your candle and can render it unusable.
To prevent candle tunneling, it is important to ensure that the entire top surface of wax is melted during each burn. The first burn is the most significant, as it sets the stage for how the candle will burn in the future. A good rule of thumb is to burn your candle for one hour per inch of its diameter. For example, if your candle has a diameter of 3 inches, you should burn it for 3 hours before putting it out.
It is also important to use the correct type of wick for your wax and fragrance combination. If the wick is too short or improperly sized, it may not be able to warm the wax from edge to edge, leading to tunneling. The wick should usually be about 1/4 inch in length for optimal burning.
Additionally, the fragrance oil used should be optimized for candle-making. Non-combustible ingredients in the fragrance oil can accumulate in the melt pool, causing the flame to go out.
If you notice tunneling, you can try to fix it by blowing out the candle as soon as you see the tunnels forming. Then, when the candle is not lit, use a hairdryer to warm the top and even out the melt distribution. For deeper tunnels, wrap tin foil around the candle's base and upper edge, leaving an opening at the top for the flame. This helps concentrate the heat and melt the outermost wax.
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Candle safety
Candlelight can be beautiful and is often used to create a cosy or romantic atmosphere. However, candles are an open flame and can be dangerous if not used properly. Here are some safety tips to follow when using candles:
Firstly, never leave a burning candle unattended. Always ensure it is within your sight and never fall asleep or leave the room while it is lit. Extinguish candles before going to bed or leaving the house. It is also important to keep candles out of reach of children and pets.
Secondly, always use a stable candle holder that is specifically designed for candle use. It should be heat-resistant, sturdy, and large enough to contain any drips or melted wax. Place candles on a flat, even surface to prevent them from tipping over. Keep burning candles at least three inches apart from each other and at least 12 inches away from anything flammable, such as curtains, paper, or furniture.
Thirdly, before lighting a candle, always trim the wick to ¼ inch. Long or crooked wicks can cause uneven burning, dripping, or flickering. Keep the wax pool clear of any debris, wick trimmings, or matches. Extinguish the candle if the flame becomes too high or flickers repeatedly. Let the candle cool, trim the wick, and check for drafts before relighting.
Finally, do not burn a candle all the way down. Discontinue use when ½ inch of wax remains in the container or 2 inches if using a pillar candle. Consider using battery-operated flameless candles, which can look, smell, and feel like real candles without the risk of an open flame.
By following these safety precautions, you can enjoy your candles while minimizing the risk of fire or other hazards.
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Frequently asked questions
A candle is made of wax, which is a hydrocarbon, and a wick, which is usually made of cotton.
The heat of the flame turns the wax into a hot gas, which breaks down into molecules of hydrogen and carbon. These molecules react with oxygen from the air to create heat, light, water vapour and carbon dioxide.
Candle tunneling occurs when a hole forms down the centre of the candle, leaving unused wax at the edges. This happens when only a small portion of the wax surrounding the wick melts.
To prevent candle tunneling, burn your candle long enough for the entire top surface of wax to melt. A good rule of thumb is to burn your candle for one hour per inch of its diameter.
A candle will go out if it loses one of the three essential ingredients for a stable flame: fuel, oxygen and heat. For example, if the wick becomes submerged in wax, it will lose oxygen and heat.


























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