
Candles are a source of light and heat, but they also emit vapors and particles into the environment. The combustion process of lighting a candle includes the release of light, heat, carbon dioxide, and water vapor, as well as volatile organic compounds that release carbon into the air. The light and heat from a candle come from the wax burning. When a candle is lit, the flame causes the wax to melt, flow up the wick, and evaporate, and it is this wax vapor that burns. The wax vapor combines with oxygen in the air to form carbon dioxide and water vapor. These gases dissipate in the air, becoming indistinguishable from other molecules of carbon dioxide and water.
| Characteristics | Values |
|---|---|
| Vapors released | Water vapor, carbon dioxide, volatile organic compounds, lead vapors (in the case of candles with lead-cored wicks) |
| Source of vapors | Vaporized wax |
| Color of flame | Blue, orange/brown, Yellow |
| Temperature of flame | 1,000 °C (1,800 °F) on average; 1,400 °C (2,550 °F) at the hottest part of the flame |
| Temperature of vaporization | 600 °C (1,112 °F) at the base of the wick |
| Energy released | Heat and light, with about one-quarter of the energy emitted as heat |
| Rate of burning | 0.1 g/min for a modern paraffin wax candle |
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What You'll Learn

How candle vapors are formed
Candlelight has been a significant source of indoor lighting for over two millennia. The combustion of a candle involves the release of light, heat, carbon dioxide, and water vapour. The light and heat from a candle come from the wax burning. When you light a candle, the flame melts the wax, which flows up the wick and evaporates, and then the wax vapour burns.
The wick, made of cotton or specially treated paper, also burns, although the wax contributes most of the heat. The flame of a candle is formed because wax vaporises on burning. The heat of the flame vaporises the liquid wax, turning it into a hot gas, and starts to break down the hydrocarbons into molecules of hydrogen and carbon. These vaporised molecules are drawn up into the flame, where they react with oxygen from the air to create heat, light, water vapour, and carbon dioxide.
The blue zone at the base of the flame is oxygen-rich, and this is where the hydrocarbon molecules vaporise and start to break apart into hydrogen and carbon atoms. The hydrogen is the first to separate here and reacts with the oxygen to form water vapour. Some of the carbon burns here to form carbon dioxide. The dark orange-brown region has relatively little oxygen. This is where the various forms of carbon continue to break down and small, hardened carbon particles start to form. As they rise, along with the water vapour and carbon dioxide created in the blue zone, they are heated to approximately 1000 degrees Centigrade.
The combustion of the candle proceeds in a self-sustaining manner. As the wick of a candle is lit, the heat melts and ignites a small amount of solid fuel (the wax), which vaporises and combines with oxygen in the air to form a flame. The flame then melts the top of the mass of solid fuel, which moves upward through the wick via capillary action to be continually burnt, thereby maintaining a constant flame. The candle shortens as the solid fuel is consumed, and so does the wick.
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Types of vapors released
The vapours released from a candle are primarily water vapour and carbon dioxide. Candle wax, also known as paraffin, is made up of hydrogen and carbon atoms, which are released as water vapour and carbon dioxide when the candle burns. The hydrogen atoms combine with oxygen in the air to form water vapour, while the carbon atoms form carbon dioxide. These gases are released into the air and become indistinguishable from other molecules of carbon dioxide and water vapour.
The combustion process of burning a candle also releases volatile organic compounds (VOCs), which can be harmful if inhaled in high doses. However, the amount of VOCs released by a candle is relatively small and comparable to the amount of carbon dioxide and water vapour produced. It is worth noting that the incomplete combustion of candle wax can lead to the production of smoke and soot, which are carbon particles that do not fully burn. These by-products can contribute to indoor air pollution and have potential health risks, especially for individuals with respiratory or cardiovascular issues.
The type of wick used in a candle can also impact the vapours released. Traditionally, wicks contained a lead core to keep them upright, but these have been largely replaced by zinc or zinc alloys due to concerns about lead vapour being released during burning. Modern wicks are often made from cotton or specially treated paper, and they can be infused with chemicals to modify their burning characteristics. For example, ammonium nitrate and ammonium sulfate are added to prevent the wick from glowing after the flame is extinguished.
The size and stability of the flame can also affect the vapours released. A longer wick can create an imbalance in the combustion process, leading to excess soot formation. Additionally, an unstable or flickering flame can cause incomplete combustion, resulting in the release of smoke and soot. To ensure a cleaner burn, it is recommended to trim the wick regularly and use a candle snuffer instead of blowing out the candle to prevent the production of smoke and soot.
Overall, while the primary vapours released from a candle are water vapour and carbon dioxide, there are other factors that can influence the types and amounts of vapours produced, such as the type of wick, the size of the flame, and the completeness of combustion. Incomplete combustion can lead to the release of smoke and soot, which may have negative impacts on indoor air quality and respiratory health. Therefore, it is important to take precautions to ensure proper burning and ventilation when using candles.
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Health and environmental concerns
Burning candles emit volatile organic compounds, including carbon dioxide and water vapour, into the environment. While carbon dioxide and water are normal parts of the air, too much of either can be dangerous. However, the amount of gas produced by a candle is small and comparable to the amount exhaled by another person in the room.
The combustion process of lighting a candle releases light, heat, carbon dioxide, and water vapour. The light and heat from a candle come from the wax burning. When a candle is lit, the flame causes some of the wax to melt, flow up the wick and evaporate, and then the wax vapour burns. The wick, usually made of cotton, also burns, but the wax contributes most of the heat. The puddles sometimes seen around the base of a candle are from wax that spilled and dripped down without burning.
Wicks are often infused with chemicals to modify their burning characteristics. Historically, wicks contained a lead core to keep them upright in container candles. Without this, the wicks would sag and drown in the wax pool. However, lead wicks presented a known health and developmental hazard as the lead could vaporize during burning and release lead vapours. Lead core wicks have not been common since the 1970s, with most metal-cored wicks now using zinc or a zinc alloy. Safer wicks are made from specially treated paper and cotton.
Smoke and soot are byproducts of incomplete combustion. Soot is a chalk-like black substance made of carbon particles. Incomplete combustion occurs when the wax melts faster than it can fuel the flame, creating an imbalance. This can be caused by a long wick, which creates a bigger and hotter flame, or by a flickering flame due to a room with large amounts of airflow. To avoid this, wicks should be trimmed regularly, and candles should be extinguished with a snuffer rather than blown out. Blowing out a candle produces a small burst of smoke and soot that can damage the wick.
Constant exposure to the tiny particles in candle smoke and soot can lead to cardiovascular and respiratory diseases. For people who burn candles occasionally, the fire hazards may be a bigger concern than the air pollution. However, non-toxic candles made from coconut, soy, vegetable, and beeswax are available as alternatives.
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Factors influencing vapor release
The vapor released from a candle is primarily water vapour and carbon dioxide, with minimal soot. The amount of vapour released depends on several factors, including the type of wax, the completeness of combustion, the size of the wick, and the presence of additives or fragrances.
The type of wax used in a candle affects the amount and type of vapour released. Paraffin wax, a common candle wax derived from crude oil, is a hydrocarbon that vaporises and burns when heated, releasing water vapour and carbon dioxide. Candles made from natural waxes like soy, coconut, vegetable, or beeswax may produce less soot and have better burn quality due to their lower melting points.
Complete combustion of candle wax results in the formation of water vapour and carbon dioxide, with minimal soot production. Incomplete combustion, indicated by a flickering flame or smoke, releases unburned soot particles and contributes to indoor air pollution. Maintaining a stable flame and ensuring complete combustion can be achieved through proper wick trimming and avoiding excessive airflow.
The size and material of the wick influence the rate of wax melting and vapour release. A larger exposed wick increases the flame size and heat, affecting the combustion process and potentially leading to excess soot production. Commercial wicks are typically made from braided cotton and may be infused with chemicals like ammonium nitrate or ammonium sulfate to modify burning characteristics and prevent glowing after extinguishing.
Additives and fragrances in candles can introduce volatile organic compounds (VOCs) into the air during burning. These compounds can be harmful when inhaled at high concentrations. Non-toxic candles made with alternative wax blends, safe fragrances, and eco-friendly packaging are available as healthier alternatives.
The presence of a glass candle holder can also impact vapour release. Thermal shock from the flame can crack the glass, especially when the candle burns down to the end. Using cracked containers or allowing the wax to burn too low can be unsafe.
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Alternatives to candles with vapors
Candles are a great way to create a cosy atmosphere and fill your home with fragrance. However, they can be a fire hazard and the vapours released when a candle burns—carbon dioxide and water vapour—can be harmful to health in large quantities. If you're concerned about the effects of candle vapours, here are some alternatives to consider:
Electric Flameless Candles
For those who seek the aesthetics of a candle without the hazards, electric flameless candles are a great option. These candles use a small LED light to mimic the flicker of a real flame, creating a cosy atmosphere without the risk of fire or exposure to candle vapours.
Wax Warmers
Wax warmers, also known as electric warmers or plate candle warmers, are devices that melt scented candles from the bottom up, releasing fragrance without the need for a flame. This option allows you to enjoy the scent of your favourite candles while preserving the wax.
Reed Diffusers
Reed diffusers offer a long-lasting alternative to scented candles. They typically consist of a vessel filled with fragrance oil and thin reeds. The reeds soak up the fragrance and disperse it into the air through evaporation. A 6-ounce reed diffuser can offer fragrance for up to 4 months, while larger sizes can last even longer.
Essential Oil Diffusers
Essential oil diffusers allow you to create your own fragrance blends and swap scents based on your preferences. You can use high-quality essential oils made with natural ingredients, ensuring that you're releasing only safe and beneficial fragrances into the air. Smart diffusers, like the PURA Smart Device, offer customisable fragrance experiences that can be controlled through smartphone apps.
Natural or Non-Toxic Candles
If you're not ready to give up traditional candles just yet, you can opt for natural or non-toxic candles made from coconut, soy, vegetable, or beeswax. These candles use essential or natural oils for fragrance, avoiding the potentially harmful chemicals found in synthetic fragrances. Companies like "The Plant Project" offer environmentally sustainable and lung-healthy candles with non-toxic wax blends, safe fragrances, and eco-friendly packaging.
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Frequently asked questions
When a candle burns, the wax transforms into a gas and releases water vapour and carbon dioxide.
Candles are made from wax, which is a hydrocarbon called paraffin derived from crude oil.
Smoke from a candle is caused by unburned soot particles that escape the flame due to incomplete combustion.
Candle soot is made of carbon particles that form through a series of complex chemical reactions.
Candle use can be unsafe if fragrances are inhaled at high doses. Candles also emit volatile organic compounds, releasing carbon into the air. However, non-toxic candles made from coconut, soy, vegetable, and beeswax are available as safer alternatives.











































