
Burning candles has fascinated scientists for hundreds of years. Candle wax is made of hydrogen and carbon atoms (hydrocarbons). When a candle burns, the wax melts and moves up the wick, where it evaporates and burns. The hydrogen and carbon molecules react with oxygen in the air to form carbon dioxide (CO2) and water vapour. The carbon dioxide and water vapour produced during combustion cool and mix into the air in the room, eventually dispersing into the atmosphere. However, incomplete combustion can lead to the formation of soot and smoke.
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What You'll Learn

Candle burning is a combustion reaction
The hydrogen and carbon molecules in the wax turn into gas and react with the oxygen in the air to form carbon dioxide and water vapour. This reaction releases energy in the form of heat and light. The carbon dioxide and water vapour cool and mix into the air in the room, becoming indistinguishable from other molecules. Over time, as the air in the room is exchanged with outdoor air, the molecules from the candle escape and disperse into the atmosphere.
The combustion process of a candle involves phase changes, where the wax transitions from a solid to a liquid and then to a gas. This process results in an even burn when the wax melts at the same rate that it fuels the flame. However, incomplete combustion can occur when there is an imbalance, leading to smoke and soot formation. The blue area at the base of the flame is oxygen-rich, where hydrocarbon molecules vaporise and break apart into hydrogen and carbon atoms. The hydrogen reacts with oxygen to form water vapour, while some of the carbon burns to form carbon dioxide.
The dark orange-brown region above the blue zone has relatively less oxygen. Here, various forms of carbon continue to break down, forming small, hardened carbon particles. These particles rise with the water vapour and carbon dioxide, heating up to approximately 1000 degrees Celsius. At the bottom of the yellow zone, the formation of carbon soot particles increases, and as they rise and heat up, they ignite and emit visible light. The yellow portion of the spectrum dominates when the carbon ignites, giving the flame its yellowish appearance.
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CO2 is produced when hydrogen and carbon molecules react with oxygen
The combustion of candle wax, which is made of hydrogen and carbon atoms, results in the production of carbon dioxide (CO2) and water vapour. This occurs through the reaction of hydrogen and carbon molecules with oxygen.
When a candle burns, the heat of the flame causes the wax to melt and move up the wick, where it then evaporates and burns. The combustion of candle wax is a chemical reaction that produces heat, light, and invisible byproducts. This process is known as a convection current, where the flame heats the nearby air, causing it to rise and be replaced by cooler air and oxygen at the bottom of the flame. This cycle of upward-moving air gives the flame its teardrop shape.
In the combustion reaction, the hydrogen and carbon molecules from the wax react with the oxygen in the air. This reaction forms carbon dioxide and water vapour, releasing energy in the form of heat and light. The carbon dioxide and water vapour produced cool and mix into the surrounding air, becoming indistinguishable from other molecules. Over time, these molecules disperse into the atmosphere as the air in the room is exchanged with outdoor air.
The specific chemical reaction between hydrogen, carbon, and oxygen molecules results in the formation of carbon dioxide and water vapour. The hydrogen molecules are the first to separate from the hydrocarbon molecules in the oxygen-rich blue zone of the flame. These hydrogen molecules react with oxygen to form water vapour. Some of the carbon atoms also burn in this zone, producing carbon dioxide. As the carbon particles continue to break down and rise, they are heated to high temperatures, reaching incandescence and emitting visible light.
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CO2 and water vapour cool and mix into the room's air
When a candle burns, the wax melts and the hydrogen and carbon molecules in the wax react with the oxygen in the air. This reaction produces carbon dioxide (CO2) and water vapour. The light and heat from the candle come from this combustion reaction.
The combustion reaction of a candle burning produces heat, which causes the nearby air to rise. As the warm air moves up, cooler air and oxygen rush in at the bottom of the flame to replace it. This creates a convection current, giving the flame its teardrop shape. However, this process also results in incomplete combustion, where clumps of carbon molecules are flung away, contributing to smoke and soot.
The CO2 and water vapour produced by the candle flame will initially be hot, but they will cool down and mix into the room's air. Over time, as the room's air is exchanged with outdoor air, the CO2 and water vapour molecules will disperse into the atmosphere.
It is important to note that while burning a candle occasionally may not be a significant concern, regularly burning candles can lead to exposure to airborne particles. To minimise this exposure, it is recommended to ensure the room is well-ventilated and to use clean, white candles with fewer additives.
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Incomplete combustion results in less CO2 and more soot
The burning of a candle is a combustion reaction. When a candle burns, the heat of the flame causes the wax to melt and move up the wick, where it then evaporates and the vapour burns. The wax, which is made up of hydrogen and carbon atoms, reacts with the oxygen in the air to form carbon dioxide and water vapour. This process releases energy in the form of heat and light.
However, candles do not burn perfectly. Incomplete combustion occurs when there is insufficient oxygen for the fuel to burn completely. This results in the formation of carbon monoxide, carbon (soot), and less carbon dioxide. Incomplete combustion can also produce other compounds such as polycyclic aromatic hydrocarbons (PAHs), dioxins, and furans, which can be more toxic than the original compounds.
The dark or orange/brown region of the candle flame has relatively little oxygen. Here, the various forms of carbon continue to break down and form small, hardened carbon particles (soot). As these particles rise, they are heated to high temperatures and eventually ignite, emitting visible light. The human eye perceives the flame as yellowish due to the dominance of the yellow portion of the spectrum when the carbon ignites.
The amount of incomplete combustion can be influenced by various factors, such as the length of the exposed wick, airflow, and the type of wax used. A longer wick can result in a bigger and hotter flame, potentially leading to incomplete combustion. Drafty areas can also affect the combustion process, causing the candle flame to flicker and burn unevenly. Additionally, different types of wax have varying melting points, which can impact the rate at which the wax fuels the flame.
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CO2 can be used to put out a flame
The combustion of a candle involves the ignition of candle wax, which is made of hydrogen and carbon atoms, in the presence of oxygen. This process results in the formation of heat, light, and an oxide compound, specifically carbon dioxide (CO2) and water vapour. The light and heat from a candle are produced by the burning of wax, and the cycle continues until the wax is depleted or the flame is extinguished.
CO2 is used to put out fires and is the most commonly employed "inert" gas extinguishing agent. It is favoured for its effectiveness and the fact that it leaves no mess, unlike water, chemical, or foam-based extinguishers. CO2 fire extinguishers work by pushing oxygen away from the fire, thereby starving the flame of fuel. This property of CO2 is also the reason why it is dangerous to humans, as it can displace oxygen in the air and lead to asphyxiation.
In a demonstration, students can observe how CO2 is produced by mixing vinegar (an acid) and baking soda (a base). The resulting CO2 gas is collected in a balloon, and when released, it sinks and collects at the bottom of a glass container. This experiment showcases the invisible nature of CO2, and when poured over a flame, it effectively extinguishes it by displacing the oxygen required for combustion.
CO2 fire suppression systems have been implemented in various settings, including theatres, computer rooms, and telecommunication areas. However, there have been incidents of accidental discharges causing injuries and fatalities, highlighting the importance of adhering to safety protocols when using CO2 as a fire suppressant.
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Frequently asked questions
When a candle burns, the heat of the flame causes the wax to melt and move up the wick, where it then evaporates and the wax vapour burns. The hydrogen and carbon molecules in the wax turn into gas and react with the oxygen in the air to form carbon dioxide and water vapour.
The carbon dioxide produced by a burning candle will cool and mix into the air in the room, becoming indistinguishable from other carbon dioxide molecules. As the room's air is exchanged with outdoor air, the carbon dioxide molecules will escape and begin to disperse into the atmosphere.
Constant exposure to the particles produced by burning candles can lead to cardiovascular and respiratory issues. To minimise exposure to these particles, ensure the room is well-ventilated and opt for clean, white candles without additives.











































