
Candles are a source of comfort and ambiance for many people, but what happens to the wax that melts away? It's a common misconception that candle wax evaporates as candles burn. In reality, the heat from the flame causes the wax to melt and then vaporize. This vaporized wax doesn't disappear but reacts with oxygen in a process called combustion, producing heat, light, carbon dioxide, and water vapour. The wick, usually made of cotton, acts like a straw, drawing the liquid wax upwards towards the flame. This melted wax is the fuel that sustains the candle's flame until it's all burned away. While candles burned in moderation pose little health risk, constant exposure to the particles produced can contribute to cardiovascular and respiratory issues.
| Characteristics | Values |
|---|---|
| What happens to the melted wax | The wax melts and then vaporizes, reacting with oxygen in the air in a process called combustion. |
| What is combustion? | Combustion produces heat, light, carbon dioxide, and water vapour. |
| What is the candle fuel? | The melted wax is the fuel that keeps the candle burning. |
| What happens to the candle wick? | The wick, usually made of cotton, acts like a straw, absorbing the liquid wax and drawing it upwards towards the flame. |
| What is the ideal shape of the flame? | A teardrop-shaped flame is ideal for an efficient combustion reaction. |
| What happens if the flame is unstable? | An unstable flame can cause the candle to burn faster and increase the risk of fire. |
| What are the health risks of burning candles? | Constant exposure to candle particles can lead to cardiovascular and respiratory issues. Inhaling soot is not good for the lungs. |
| How to minimize health risks? | Ensure proper ventilation, use plain white candles, and avoid burning for more than 3-4 hours at a time. |
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What You'll Learn

The melted wax is fuel for the candle
When a candle is lit, the flame causes the wax to melt and flow up the wick, where it then evaporates and burns. The wick, usually made of cotton, acts like a straw, absorbing the liquid wax and drawing it upwards. This melted wax is the fuel that keeps the candle burning.
The wick's capillary action, or "wicking", is a crucial part of the process. The liquid wax is drawn up through the tiny spaces between the fibres of the wick. This is an example of capillary action, where a liquid is pulled or absorbed into small spaces due to attractive forces between the liquid and the solid. The wax is then vaporised by the heat of the flame, turning into a hot wax gas.
This gas, now highly reactive due to the heat, undergoes combustion when it comes into contact with oxygen in the air. This reaction produces heat, light, water vapour, and carbon dioxide. The heat generated by this reaction sustains the flame, continuing the cycle until all the wax is consumed.
The colour of the flame is influenced by the temperature and oxygen levels. The hottest part of the flame is the blue, almost invisible area near the base, where oxygen is drawn in. The flame gets cooler as you move towards the wick, with the red/orange inner part burning at around 800°C. The yellow portion of the spectrum is the most dominant when the carbon ignites, so the human eye perceives the flame as yellowish.
The size of the melt pool, or the puddle of liquid wax, is influenced by factors such as wick size and fragrance blends. If the wick is too small, the melt pool may not reach the edges of the vessel, leading to an unstable flame and reduced candle life. Proper candle care, such as trimming the wick before each burn, is important to ensure efficient burning and reduce the risk of accidents.
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It moves up the wick and vaporises
When a candle is lit, the heat from the flame melts the wax. This melted wax then travels up the wick towards the flame. The wick, usually made of cotton, acts like a straw, absorbing the liquid wax and drawing it upwards. Once the liquid wax reaches the flame, the high temperature causes it to vaporize, turning it into a hot wax gas. This process of wax transformation from solid to liquid to gas is fascinating.
The vaporized wax does not simply disappear; it undergoes a chemical reaction with the oxygen in the air, known as combustion. This reaction produces heat, light, carbon dioxide, and water vapour. The heat generated in this process sustains the flame, continuing the cycle until all the wax is consumed. The light and heat from the candle come from the burning of the wax.
The combustion process in a candle is quite efficient when the flame burns steadily with a teardrop-shaped appearance. In such cases, only carbon dioxide and water vapour are released into the air. However, if the flame receives too little or too much air or fuel, it can flicker or flare, and unburned carbon particles (soot) may escape. These unburned soot particles contribute to smoke and can be harmful if inhaled.
To minimize exposure to these airborne particles, it is recommended to ensure proper ventilation in the room and use clean, white candles with minimal additives. Additionally, keeping the wicks trimmed short and avoiding consecutive burning for extended periods can help reduce the production of soot. Following these steps can help maintain a clean and efficient burning process while minimizing the release of unburned carbon particles.
Overall, the journey of the wax in a candle involves a captivating interplay of chemistry and physics, transforming from a solid state to a gaseous one through the process of melting and vaporization.
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Vaporised wax reacts with oxygen
When a candle burns, the wax melts and flows up the wick, where it evaporates and turns into a hot wax gas. This gas, now in a highly reactive state, combusts and reacts with oxygen in the air. This reaction, known as combustion, produces heat, light, water vapour, and carbon dioxide. The heat produced in this reaction helps to sustain the flame, continuing the cycle until all the wax is consumed.
The light and heat from a candle come from the combustion of wax. The wick, usually made of cotton, acts like a straw, drawing the liquid wax upwards towards the flame. Once the liquid wax reaches the flame, the high temperature causes it to vaporize, transforming it from a solid to a gas.
The vaporized wax, now highly reactive, combines with the oxygen in the air to combust and produce light and heat. This combustion process is what sustains the flame of the candle. The specific type of wax used will determine the exact equation for wax combustion, but all equations follow a similar pattern.
The combustion of vaporized wax and oxygen results in the formation of carbon dioxide and water vapour. The carbon dioxide is formed when carbon atoms in the wax combine with oxygen. Similarly, the hydrogen atoms in the wax combine with oxygen to form water vapour. These gases are released into the air, giving the impression that the wax has disappeared.
The yellow colour of the candle flame is due to the ignition of carbon, which emits a full spectrum of visible light, with the yellow portion dominating. The blue area at the base of the flame is where oxygen-rich hydrocarbon molecules vaporize and break apart into hydrogen and carbon atoms. The hydrogen reacts with oxygen to form water vapour, while some of the carbon burns to form carbon dioxide.
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This creates carbon dioxide and water vapour
When a candle burns, it creates carbon dioxide and water vapour. This occurs through a multi-step chemical process. Firstly, the heat from the flame melts the wax, which then travels up the wick and vaporises into a gas. This hot wax gas then reacts with the oxygen in the air through a process called combustion.
During combustion, the hydrocarbon molecules in the wax break apart into hydrogen and carbon atoms. The hydrogen reacts with oxygen to form water vapour. The carbon burns to form carbon dioxide. This process is most efficient when the candle burns steadily with a teardrop-shaped flame. In this state, all that is released into the air is carbon dioxide and water vapour.
However, it is important to note that candles do not burn perfectly. Around the edges of the flame, clumps of carbon molecules are flung away before they finish burning, contributing to smoke and soot. These particles can be harmful, leading to cardiovascular and respiratory issues with constant exposure. Therefore, it is recommended to ensure proper ventilation when burning candles and to use clean, white candles with minimal additives.
The carbon dioxide and water vapour produced by the candle cool and mix into the air in the room. Over time, as the air in the room is exchanged with outdoor air, the molecules from the candle escape and begin to disperse. The amount of gas produced by a candle is relatively small and comparable to the amount exhaled by another person in the room.
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Soot particles are unburned carbon
When a candle burns, the wax melts and flows up the wick, where it then evaporates and the wax vapour burns. The light and heat from a candle are produced by the burning of the wax. The wax is made of hydrogen and carbon. When a candle burns, the hydrogen and carbon from the wax combine with the oxygen in the air to become carbon dioxide and water vapour. Most of the matter in the candle ends up as these two gases.
However, candles do not burn perfectly. The flame of a candle consists of several zones, with the oxygen-rich blue zone at the base, where hydrocarbon molecules vaporize and break apart into hydrogen and carbon atoms. The hydrogen is the first to separate and reacts with the oxygen to form water vapour. Some of the carbon burns here to form carbon dioxide.
The dark orange-brown region above the blue zone has relatively little oxygen. This is where the various forms of carbon continue to break down and small, hardened carbon particles start to form. As they rise, along with the water vapour and carbon dioxide, they are heated to approximately 1000 degrees Centigrade. At the bottom of the yellow zone, the formation of carbon (soot) particles increases. As they rise, they continue to heat up until they ignite and emit light. The yellow portion of the spectrum is the most dominant when the carbon ignites, which is why candle flames appear yellowish.
Soot is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons. It is considered a hazardous substance with carcinogenic properties. Soot always contains nanoparticles of graphite and diamond, a phenomenon known as gemmy soot. It can also include polycyclic aromatic hydrocarbons and heavy metals like mercury. The formation of soot is an issue as it is a byproduct of fossil fuel combustion, particularly from coal, and contributes to air pollution.
In the context of candles, the wisp of smoke sometimes seen when a candle flickers is caused by unburned soot particles escaping from the flame due to incomplete combustion. These unburned carbon particles contribute to smoke and soot. Constant exposure to these particles can lead to cardiovascular and respiratory diseases. Therefore, it is recommended to ensure proper ventilation when burning candles and to use clean, white candles with minimal additives.
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Frequently asked questions
The melted candle wax travels up the wick and vaporizes into a gas. This gas then reacts with oxygen in the air to produce heat, light, carbon dioxide, and water vapour.
Constant exposure to the particles released by burning candles can lead to cardiovascular and respiratory diseases. It is recommended to ensure the room is well-ventilated and to avoid burning candles consecutively for more than 3-4 hours.
The heat from the flame melts the wax, which is then drawn up the wick through a process called capillary action. The wick acts like a straw, absorbing the liquid wax and transporting it to the flame.
The rate at which candle wax is consumed depends on several factors, including the size and type of wick, the composition of the wax, and the burning conditions. For example, if the wick is too small, the melt pool may not reach the edges of the vessel, leading to an unstable flame and reduced candle life.
The blue zone at the base of the flame is where oxygen is drawn in and it is the hottest part of the flame, reaching temperatures of approximately 1400°C. This zone is oxygen-rich and it is where hydrocarbon molecules vaporize and break apart into hydrogen and carbon atoms.











































